Thursday, June 4, 2009

Epoxy Resin Research:



Epoxy or polyepoxide is a thermosetting polymer formed from reaction of an epoxide "resin" with polyamine "hardener". Epoxy has a wide range of applications, including fiber-reinforced plastic materials and general purpose adhesives.
Epoxy is a copolymer; that is, it is formed from two different chemicals. These are referred to as the "resin" and the "hardener". The resin consists of monomers or short chain polymers with an epoxide group at either end. Most common epoxy resins are produced from a reaction between epichlorohydrin and bisphenol-A, though the latter may be replaced by similar chemicals. The hardener consists of polyamine monomers, for example Triethylenetetramine (TETA). When these compounds are mixed together, the amine groups react with the epoxide groups to form a covalent bond. Each NH group can react with an epoxide group, so that the resulting polymer is heavily crosslinked, and is thus rigid and strong.
The process of polymerization is called "curing", and can be controlled through temperature and choice of resin and hardener compounds; the process can take minutes to hours. Some formulations benefit from heating during the cure period, whereas others simply require time, and ambient temperatures.

Typical room temperature properties of the unfilled anhydride cured epoxy resin system:

Tensile Strength, psi12,300

Tensile Modulus, psi x 105450,000

Elongation %6%

Flexural Strength, psi12,000

Flexural Modulus, psi x 105425,000

Heat Distortion Temperature265o

Service Temperature255oF or 325oF

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